La Libertad is politically subdivided into 29 barangays.
* Aniniaw
* Aya
* Bagtic
* Biga-a
* Busilak
* Cangabo
* Cantupa
* Eli
* Guihob
* Kansumandig
* Mambulod
* Mandapaton
* Manghulyawon
* Manluminsag
* Mapalasan
* Maragondong
* Martilo
* Nasungan
* Pacuan
* Pangca
* Pisong
* Pitogo
* Poblacion North
* Poblacion South
* San Jose
* Solongon
* Tala-on
* Talayong
* Elecia
